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锶/氟生物活性玻璃纳米颗粒和磷酸钙对用于核桩修复材料的双固化牙科复合材料的单体转化率、双轴弯曲强度、表面显微硬度、质量/体积变化及颜色稳定性的影响

Effects of Sr/F-Bioactive Glass Nanoparticles and Calcium Phosphate on Monomer Conversion, Biaxial Flexural Strength, Surface Microhardness, Mass/Volume Changes, and Color Stability of Dual-Cured Dental Composites for Core Build-Up Materials.

作者信息

Mirchandani Bharat, Padunglappisit Chawal, Toneluck Arnit, Naruphontjirakul Parichart, Panpisut Piyaphong

机构信息

Faculty of Dentistry, Thammasat University, Pathum Thani 12120, Thailand.

Biological Engineering Program, Faculty of Engineering, King Mongkut's University of Technology Thonburi, Bangkok 10140, Thailand.

出版信息

Nanomaterials (Basel). 2022 Jun 1;12(11):1897. doi: 10.3390/nano12111897.

Abstract

This study prepared composites for core build-up containing Sr/F bioactive glass nanoparticles (Sr/F-BGNPs) and monocalcium phosphate monohydrate (MCPM) to prevent dental caries. The effect of the additives on the physical/mechanical properties of the materials was examined. Dual-cured resin composites were prepared using dimethacrylate monomers with added Sr/F-BGNPs (5 or 10 wt%) and MCPM (3 or 6 wt%). The additives reduced the light-activated monomer conversion by 10%, but their effect on the conversion upon self-curing was negligible. The conversions of light-curing or self-curing polymerization of the experimental materials were greater than that of the commercial material. The additives reduced biaxial flexural strength (191 to 155 MPa), modulus (4.4 to 3.3), and surface microhardness (53 to 45 VHN). These values were comparable to that of the commercial material or within the acceptable range of the standard. The changes in the experimental composites' mass and volume (1%) were similar to that of the commercial comparison. The color change of the commercial material (1.0) was lower than that of the experimental composites (1.5-5.8). The addition of Sr/F-BGNPs and MCPM negatively affected the physical/mechanical properties of the composites, but the results were satisfactory except for color stability.

摘要

本研究制备了含锶/氟生物活性玻璃纳米颗粒(Sr/F-BGNPs)和一水磷酸二氢钙(MCPM)的用于核修复的复合材料,以预防龋齿。研究了添加剂对材料物理/机械性能的影响。使用添加了Sr/F-BGNPs(5或10 wt%)和MCPM(3或6 wt%)的二甲基丙烯酸酯单体制备了双固化树脂复合材料。添加剂使光活化单体转化率降低了约10%,但它们对自固化时转化率的影响可忽略不计。实验材料的光固化或自固化聚合转化率高于商业材料。添加剂降低了双轴弯曲强度(从191 MPa降至155 MPa)、模量(从4.4降至3.3)和表面显微硬度(从53 VHN降至45 VHN)。这些值与商业材料相当或在标准的可接受范围内。实验复合材料的质量和体积变化(约1%)与商业对照材料相似。商业材料的颜色变化(1.0)低于实验复合材料(1.5 - 5.8)。添加Sr/F-BGNPs和MCPM对复合材料的物理/机械性能有负面影响,但除颜色稳定性外,结果令人满意。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1773/9181985/464627106afc/nanomaterials-12-01897-g001.jpg

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