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光活性卷曲二氧化钛微管:制备、表征及应用† 可获取电子补充信息(ESI)。见DOI: 10.1039/c4tc00796d 点击此处获取额外数据文件。

Photoactive rolled-up TiO microtubes: fabrication, characterization and applications†Electronic supplementary information (ESI) available. See DOI: 10.1039/c4tc00796dClick here for additional data file.

作者信息

Giudicatti Silvia, Marz Sonja M, Soler Lluís, Madani Abbas, Jorgensen Matthew R, Sanchez Samuel, Schmidt Oliver G

机构信息

Institute for Integrative Nanosciences , IFW Dresden , Helmholtzstraße 20 , 01069 Dresden , Germany . Email:

出版信息

J Mater Chem C Mater. 2014 Aug 7;2(29):5892-5901. doi: 10.1039/c4tc00796d. Epub 2014 Jun 20.

Abstract

Because of its unique properties, titania (TiO) represents a promising candidate in a wide variety of research fields. In this paper, some of the properties and potential applications of titania within rolled-up nanotechnology are explored. It is shown how the structural and optical properties of rolled titania microtubes can be controlled by properly tuning the microfabrication parameters. The rolling up of titania films on different sacrificial layers and containing different shapes, achieving a control on the diameter of the fabricated titania microtubes, is presented. In order to obtain the more photoactive crystalline form of titania, one during-fabrication and two post-fabrication methods are demonstrated. Interesting applications in the fields of photocatalysis and photonics are suggested: the use of titania rolled-up microtubes as micromotors and optical microresonators is presented.

摘要

由于其独特的性质,二氧化钛(TiO)在众多研究领域中都是一个有前景的候选材料。本文探讨了二氧化钛在卷对卷纳米技术中的一些性质和潜在应用。展示了如何通过适当调整微加工参数来控制卷状二氧化钛微管的结构和光学性质。介绍了在不同牺牲层上卷绕含有不同形状的二氧化钛薄膜,从而实现对所制备二氧化钛微管直径的控制。为了获得更具光活性的二氧化钛晶体形式,展示了一种制备过程中的方法和两种制备后的方法。还提出了在光催化和光子学领域的有趣应用:介绍了将卷状二氧化钛微管用作微马达和光学微谐振器。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5053/4285103/d8921ff052c2/c4tc00796d-f2.jpg

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