关于纯硼酸原脱硼反应的一种机理推测：固态下硼酸介导的反应
A mechanistic proposal for the protodeboronation of neat boronic acids: boronic acid mediated reaction in the solid state.
作者信息
Noonan Gary, Leach Andrew G
机构信息
AstraZeneca, Alderley Park, Macclesfield, SK10 4TG, UK.
出版信息
Org Biomol Chem. 2015 Mar 7;13(9):2555-60. doi: 10.1039/c4ob02543a.
PMID:25604694
Abstract
A combined experimental and computational study suggests that a reduction in the entropy of activation in the solid state can lead to the protodeboronation of boronic acids.
摘要
一项结合实验和计算的研究表明，固态下活化熵的降低可能导致硼酸的原脱硼反应。
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