Kettner Marcos A, Klapötke Thomas M
Department of Chemistry, Ludwig-Maximilian University of Munich (LMU), Butenandtstrasse 5-13, House D, 81377 Munich (Germany).
Chemistry. 2015 Feb 23;21(9):3755-65. doi: 10.1002/chem.201405659. Epub 2015 Jan 21.
This combined experimental, theoretical and comparative study details the syntheses and chemical characterisation of two new energetic polynitromethyl tetrazole derivatives, namely, 2-(2-nitro-2-azapropyl)-5-(trinitromethyl)-2 H-tetrazole and its fluorine-containing analogue 2-(2-nitro-2-azapropyl)-5-(fluorodinitromethyl)-2 H-tetrazole. Their crystal structures and energetic behaviour are compared to those of their starting materials, the ammonium salts of the corresponding 5-(polynitromethyl)-2 H-tetrazoles. Additionally, the crystal structures of two further related polynitrotetrazoles are presented.
这项结合实验、理论和比较研究详细阐述了两种新型含能多硝基甲基四唑衍生物的合成及化学表征，即2-(2-硝基-2-氮杂丙基)-5-(三硝基甲基)-2 H-四唑及其含氟类似物2-(2-硝基-2-氮杂丙基)-5-(氟二硝基甲基)-2 H-四唑。将它们的晶体结构和能量行为与其起始原料，即相应的5-(多硝基甲基)-2 H-四唑的铵盐进行了比较。此外，还给出了另外两种相关多硝基四唑的晶体结构。
