Singh Ashish, Spak Scott N, Stone Elizabeth A, Downard Jared, Bullard Robert, Pooley Mark, Kostle Pamela A, Mainprize Matthew W, Wichman Michael D, Peters Thomas, Beardsley Douglas, Stanier Charles O
Chemical and Biochemical Engineering, University of Iowa, Iowa City, IA 52242.
Public Policy Center, University of Iowa, Iowa City, IA 52242.
Atmos Environ (1994). 2015 Mar;104:273-283. doi: 10.1016/j.atmosenv.2015.01.002.
The Iowa City Landfill in eastern Iowa, United States, experienced a fire lasting 18 days in 2012, in which a drainage layer of over 1 million shredded tires burned, generating smoke that impacted the surrounding metropolitan area of 130,000 people. This emergency required air monitoring, risk assessment, dispersion modeling, and public notification. This paper quantifies the impact of the fire on local air quality and proposes a monitoring approach and an Air Quality Index (AQI) for use in future tire fires and other urban fires. Individual fire pollutants are ranked for acute and cancer relative risks using hazard ratios, with the highest acute hazard ratios attributed to SO, particulate matter, and aldehydes. Using a dispersion model in conjunction with the new AQI, we estimate that smoke concentrations reached unhealthy outdoor levels for sensitive groups out to distances of 3.1 km and 18 km at 24-h and 1-h average times, respectively. Modeled and measured concentrations of PM from smoke and other compounds such as VOCs and benzo[a]pyrene are presented at a range of distances and averaging times, and the corresponding cancer risks are discussed. Through reflection on the air quality response to the event, consideration of cancer and acute risks, and comparison to other tire fires, we recommend that all landfills with shredded tire liners plan for hazmat fire emergencies. A companion paper presents emission factors and detailed smoke characterization.
美国爱荷华州东部的爱荷华市垃圾填埋场在2012年发生了一场持续18天的火灾,其中超过100万个切碎轮胎的排水层燃烧,产生的烟雾影响了周边拥有13万人的大都市区。这场紧急情况需要进行空气监测、风险评估、扩散建模和公众通知。本文量化了火灾对当地空气质量的影响,并提出了一种监测方法和空气质量指数(AQI),以供未来轮胎火灾和其他城市火灾使用。利用危害比将个别火灾污染物按急性和癌症相对风险进行排序,急性危害比最高的是二氧化硫、颗粒物和醛类。结合新的空气质量指数使用扩散模型,我们估计,在24小时和1小时平均时间下,烟雾浓度分别在3.1公里和18公里的距离内达到了对敏感人群不健康的室外水平。给出了在一系列距离和平均时间下烟雾中颗粒物以及其他化合物(如挥发性有机化合物和苯并[a]芘)的模拟浓度和测量浓度,并讨论了相应的癌症风险。通过反思该事件的空气质量响应、考虑癌症和急性风险,并与其他轮胎火灾进行比较,我们建议所有设有切碎轮胎衬里的垃圾填埋场制定危险材料火灾紧急情况预案。一篇配套论文介绍了排放因子和详细的烟雾特征。