Department of Civil and Environmental Engineering, The University of Auckland, Auckland 1142, New Zealand.
Department of Civil and Environmental Engineering, The University of Auckland, Auckland 1142, New Zealand.
Sci Total Environ. 2015 Apr 15;512-513:682-685. doi: 10.1016/j.scitotenv.2015.01.061. Epub 2015 Jan 26.
Biochar is being considered for environmental sustainability by the scientific community and as a result is extensively investigated for various applications in agriculture, remediation and construction. Hence, a sound knowledge of biochar's physical and chemical properties is critical. However, the dynamics of biochar-water interaction remain ambiguous. We hypothesize that the hydrophobicity of a biochar made at low pyrolysis temperature is not permanent under water-rich conditions. Our results suggest that the aliphatic functional groups responsible for biochar's hydrophobicity are displaced when subjected to water which eventually increases the affinity of the biochar towards water. We envisage that commentary would stimulate researchers to investigate the biochar-water interaction in a new light and eventually help design a biochar which would be apt for their intended end use.
生物炭正受到科学界的关注,被认为有助于环境可持续发展,因此被广泛研究应用于农业、修复和建筑等各个领域。因此,对生物炭物理和化学性质的深入了解至关重要。然而,生物炭与水相互作用的动态仍然不清楚。我们假设,在富水条件下,由低温热解制成的生物炭的疏水性不是永久性的。我们的研究结果表明,生物炭疏水性所依赖的脂肪族官能团在遇到水时会被取代,这最终会增加生物炭对水的亲和力。我们设想,这一观点将激发研究人员以新的视角研究生物炭与水的相互作用,并最终有助于设计出适合预期用途的生物炭。