Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, College of Life and Environmental Science, Shanghai Normal University , Shanghai, 200234, People's Republic of China.
ACS Appl Mater Interfaces. 2015 Mar 4;7(8):4533-40. doi: 10.1021/am5088665. Epub 2015 Feb 18.
Fullerene (C60) enhanced mesoporous CdS/TiO2 architectures were fabricated by an evaporation induced self-assembly route together with an ion-exchanged method. C60 clusters were incorporated into the pore wall of mesoporous CdS/TiO2 with the formation of C60 enhanced CdS/TiO2 hybrid architectures, for achieving the enhanced photostability and photocatalytic activity in H2 evolution under visible-light irradiation. Such greatly enhanced photocatalytic performance and photostability could be due to the strong combination and heterojunctions between C60 and CdS/TiO2. The as-formed C60 cluster protection layers in the CdS/TiO2 framework not only improve the light absorption capability, but also greatly accelerated the photogenerated electron transfer to C60 clusters for H2 evolution.
富勒烯（C60）增强的介孔 CdS/TiO2 结构通过蒸发诱导自组装路线和离子交换方法制备而成。C60 簇被掺入介孔 CdS/TiO2 的孔壁中，形成 C60 增强的 CdS/TiO2 杂化结构，以实现在可见光照射下 H2 释放中的光稳定性和光催化活性的增强。这种光催化性能和光稳定性的大大增强可能归因于 C60 和 CdS/TiO2 之间的强结合和异质结。在 CdS/TiO2 框架中形成的 C60 簇保护层不仅提高了光吸收能力，而且还大大加速了光生电子向 C60 簇的转移以用于 H2 释放。
