State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, China.
J Am Chem Soc. 2015 Feb 25;137(7):2480-3. doi: 10.1021/jacs.5b00719. Epub 2015 Feb 17.
A novel palladium-catalyzed intermolecular aminocarbonylation of alkenes has been developed in which the employment of hypervalent iodine reagent can accelerate the intermolecular aminopalladation, which thus provides the successful catalytic transformation. The current transformation presents one of the most convenient methods to generate β-amino acid derivatives from simple alkenes.
一种新型的钯催化烯烃分子间氨基甲酰化反应已经被开发出来，其中高价碘试剂的使用可以加速分子间的氨钯化反应，从而提供了成功的催化转化。目前的转化为从简单烯烃生成β-氨基酸衍生物提供了最方便的方法之一。
