El Sayed Sameh, Milani Michele, Licchelli Maurizio, Martínez-Máñez Ramón, Sancenón Félix
Centro de Reconocimiento Molecular y Desarrollo Tecnológico (IDM), Unidad Mixta Universidad Politécnica de Valencia, Universidad de Valencia (Spain); Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera s/n, 46022, Valencia (Spain); CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN); Dipartimento di Chimica, Università di Pavia via Taramelli 12, 27100 Pavia (Italy).
Chemistry. 2015 May 4;21(19):7002-6. doi: 10.1002/chem.201500360. Epub 2015 Mar 10.
Cu(II) -macrocycle functionalized hexametaphosphate-capped silica mesoporous nanoparticles have been prepared and used for the selective and sensitive detection of hydrogen sulfide in aqueous environments. The possibility of using different metal complexes combined with different capping anions and choice of different dyes or other sensing molecules as indicators makes this new protocol highly appealing for the preparation of new sensing systems for sulfide detection in different environments.
已制备出铜（II）-大环功能化六偏磷酸根封端的二氧化硅介孔纳米颗粒，并将其用于在水性环境中选择性和灵敏地检测硫化氢。结合不同封端阴离子使用不同金属配合物以及选择不同染料或其他传感分子作为指示剂的可能性，使得这一新方案对于制备用于不同环境中硫化物检测的新型传感系统极具吸引力。
