†State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China.
‡State Key Laboratory of Elemento-Organic Chemistry, NanKai University, Tianjin 300071, P. R. China.
Org Lett. 2015 Apr 17;17(8):2034-7. doi: 10.1021/acs.orglett.5b00844. Epub 2015 Apr 2.
An efficient method of Pd(II)-catalyzed P(O)R(1)R(2)-directed asymmetric C-H activation and dynamic kinetic resolution for synthesis of chiral phosphinate ligands has been performed and exhibits a wide scope of substrates and an excellent diastereomeric ratio (>95:5).
已开发出一种高效的 Pd(II)-催化 P(O)R(1)R(2)-导向的不对称 C-H 活化和动态动力学拆分方法，用于合成手性膦酸酯配体，具有广泛的底物范围和优异的非对映选择性 (>95:5)。
