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2,2'-（1,2-亚苯基二硫代）二乙酸银（I）作为银（I）-镉（II）配位聚合物的分子构建单元

Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer.

作者信息

Grosu Ioana Georgeta, Berghof Christiane, Lönnecke Peter, Silaghi-Dumitrescu Luminita, Hey-Hawkins Evamarie

机构信息

Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany.

Department of Chemistry, Babeş-Bolyai University, Kogalniceanu 1, RO-400084 Cluj-Napoca, Romania.

出版信息

Molecules. 2015 May 4;20(5):8020-32. doi: 10.3390/molecules20058020.

DOI:10.3390/molecules20058020
PMID:25946559
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6272712/
Abstract

Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)2-κ2S,S'}2]BF4 (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag2Cd2{1,2-(OOCCH2S)2C6H4}3 (H2O)3·5H2O]n (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques.

摘要

从异位多齿配体2,2'-(1,2-苯二硫二乙酸)出发，制备了(RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)2-κ2S,S'}2]BF4(1)，并将其进一步用作合成异双金属Ag-Cd配位聚合物[Ag2Cd2{1,2-(OOCCH2S)2C6H4}3(H2O)3·5H2O]n(2)的结构单元。通过X射线结构分析和传统光谱技术对这两种配合物进行了表征。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78f0/6272712/89a6b9b576c6/molecules-20-08020-g005a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78f0/6272712/87addf4c3234/molecules-20-08020-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78f0/6272712/3cfff0ff2089/molecules-20-08020-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78f0/6272712/c8644990d0ff/molecules-20-08020-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78f0/6272712/c0f48f5d2939/molecules-20-08020-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78f0/6272712/e13ec029b9b9/molecules-20-08020-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78f0/6272712/89a6b9b576c6/molecules-20-08020-g005a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78f0/6272712/87addf4c3234/molecules-20-08020-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78f0/6272712/3cfff0ff2089/molecules-20-08020-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78f0/6272712/c8644990d0ff/molecules-20-08020-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78f0/6272712/c0f48f5d2939/molecules-20-08020-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78f0/6272712/e13ec029b9b9/molecules-20-08020-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78f0/6272712/89a6b9b576c6/molecules-20-08020-g005a.jpg

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