Department of Physics, Osmania University, Hyderabad 500007, India.
Department of Chemical Engineering Technology, Doornfontein Campus, University of Johannesburg, Johannesburg, South Africa.
Carbohydr Polym. 2015;127:110-5. doi: 10.1016/j.carbpol.2015.03.054. Epub 2015 Mar 28.
Cellulose was dissolved in pre cooled environment friendly solvent (aq.7% sodium hydroxide+12% urea) and regenerated with 5%H2SO4 as coagulation bath. Using cellulose as matrix and alkali treated short natural fibers extracted from the newly identified Thespesia lampas plant as fillers the green composite films were prepared. The films were found to be non toxic. The effect of fiber loading on the tensile properties and thermal stability was studied. The fractographs indicated better interfacial bonding between the fibers and cellulose. The crystallinity of the composite films was found to be lower than the matrix and decreased with increasing fiber content. In spite of better interfacial bonding, the tensile properties of the composites were found to be lower than those of the matrix and decreased with increasing fiber content and this behavior was attributed to the random orientation of the fibers in the composites. The thermal stability of the composite films was higher than the matrix and increased with fiber content.
纤维素在预冷却的环保溶剂(7%氢氧化钠+12%尿素的水溶液)中溶解,然后用 5%H2SO4 作为凝固浴进行再生。以纤维素为基体,以从新鉴定的 Thespesia lampas 植物中提取的经过碱处理的短天然纤维作为填充剂,制备了绿色复合薄膜。这些薄膜被证明是无毒的。研究了纤维负载对拉伸性能和热稳定性的影响。断口形貌表明纤维与纤维素之间具有更好的界面结合。复合薄膜的结晶度低于基体,并且随着纤维含量的增加而降低。尽管具有更好的界面结合,但复合材料的拉伸性能却低于基体,并且随着纤维含量的增加而降低,这种行为归因于复合材料中纤维的随机取向。复合薄膜的热稳定性高于基体,并且随着纤维含量的增加而增加。