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染色戟叶大戟的植物化学成分及其化学分类学意义

Phytochemical constituents and chemosystematic significance of Chrozophora tinctoria (L.) Raf.

作者信息

Marzouk Mona M, Hussein Sameh R, Kassem Mona E S, Kawashty Salwa A, El Negoumy Sabry I M

机构信息

a Department of Phytochemistry and Plant Systematics , National Research Centre , Cairo 12622 , Egypt.

出版信息

Nat Prod Res. 2016 Jul;30(13):1537-41. doi: 10.1080/14786419.2015.1045506. Epub 2015 Jun 29.

DOI:10.1080/14786419.2015.1045506
PMID:26119079
Abstract

Twelve compounds were isolated from Chrozophora tinctoria (L.) Raf. They were identified as kaempferol, kaempferol 3-O-β-glucopyranoside, kaempferol 3-O-(6″-α-rhamnopyranosyl)-β-glucopyranoside, quercetin, quercetin 3-O-β-glucopyranoside, quercetin 3-O-(6″-α-rhamnopyranosyl)-β-glucopyranoside, apigenin, apigenin 7-O-β-glucopyranoside, acacetin, gallic acid, methyl gallate and β-sitosterol-3-O-β-glucopyranoside. Their structures were elucidated by chemical and spectral methods. Furthermore, chemosystematics of the isolated compounds is briefly discussed. It was indicated that C. tinctoria is the only species of Chrozophora that has the capability to synthesis kaempferol aglycone and their glycosides, and the finding is supported by its distinct morphological and anatomical aspects.

摘要

从染用戟叶大戟(Chrozophora tinctoria (L.) Raf.)中分离出了12种化合物。它们被鉴定为山奈酚、山奈酚3 - O - β - 吡喃葡萄糖苷、山奈酚3 - O -(6″ - α - 鼠李吡喃糖基)- β - 吡喃葡萄糖苷、槲皮素、槲皮素3 - O - β - 吡喃葡萄糖苷、槲皮素3 - O -(6″ - α - 鼠李吡喃糖基)- β - 吡喃葡萄糖苷、芹菜素、芹菜素7 - O - β - 吡喃葡萄糖苷、刺槐素、没食子酸、没食子酸甲酯和β - 谷甾醇 - 3 - O - β - 吡喃葡萄糖苷。通过化学和光谱方法阐明了它们的结构。此外,还简要讨论了分离出的化合物的化学分类学。结果表明,染用戟叶大戟是戟叶大戟属中唯一能够合成山奈酚苷元和其糖苷的物种,这一发现得到了其独特的形态学和解剖学特征的支持。

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