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离子液体辅助合成TON型沸石

Ionic Liquid assisted Synthesis of Zeolite-TON.

作者信息

Tian Yuyang, McPherson Matthew J, Wheatley Paul S, Morris Russell E

机构信息

EaSt Chem. School of Chemistry, University of St Andrews Purdie Building, St Andrews KY16 9ST, UK.

出版信息

Z Anorg Allg Chem. 2014 May;640(6):1177-1181. doi: 10.1002/zaac.201400103. Epub 2014 Mar 20.

DOI:10.1002/zaac.201400103
PMID:26213423
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4502969/
Abstract

An ionic liquid assisted strategy for the synthesis of zeolitic material is reported. This strategy is a solid state synthetic method and the ionic liquid is employed as structure directing agent. A TON-type zeolite, which contains one-dimensional 10-member-ring, is successfully synthesized with the assistance of the ionic liquid, 1-ethyl-3-methylimidazolium bromide. This finding improves our understanding about the challenge of ionothermally synthesizing siliceous and aluminosilicate zeolites.

摘要

报道了一种用于合成沸石材料的离子液体辅助策略。该策略是一种固态合成方法，离子液体用作结构导向剂。在离子液体1-乙基-3-甲基咪唑溴化物的辅助下，成功合成了一种含有一维十元环的TON型沸石。这一发现增进了我们对离子热合成硅质和铝硅酸盐沸石挑战的理解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/285b48fc4d54/zaac0640-1177-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/088903a880dd/zaac0640-1177-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/04a2d5742969/zaac0640-1177-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/4e93671ea9a6/zaac0640-1177-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/33929e5cf586/zaac0640-1177-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/6d7a45bf0a03/zaac0640-1177-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/7d1d4f024713/zaac0640-1177-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/285b48fc4d54/zaac0640-1177-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/088903a880dd/zaac0640-1177-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/04a2d5742969/zaac0640-1177-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/4e93671ea9a6/zaac0640-1177-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/33929e5cf586/zaac0640-1177-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/6d7a45bf0a03/zaac0640-1177-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/7d1d4f024713/zaac0640-1177-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a92b/4502969/285b48fc4d54/zaac0640-1177-f7.jpg

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