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将掺氮 TiO2 纳米棒纳入由回收报纸制成的再生纤维素薄膜中,作为一种绿色可携式光触媒。

Incorporation of N-doped TiO2 nanorods in regenerated cellulose thin films fabricated from recycled newspaper as a green portable photocatalyst.

机构信息

Advanced Membrane Technology Research Centre, Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru, Malaysia; Faculty of Petroleum and Renewable Energy Engineering, Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru, Malaysia.

Advanced Membrane Technology Research Centre, Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru, Malaysia; Faculty of Petroleum and Renewable Energy Engineering, Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru, Malaysia.

出版信息

Carbohydr Polym. 2015 Nov 20;133:429-37. doi: 10.1016/j.carbpol.2015.07.057. Epub 2015 Jul 23.

DOI:10.1016/j.carbpol.2015.07.057
PMID:26344299
Abstract

In this work, an environmental friendly RC/N-TiO2 nanocomposite thin film was designed as a green portable photocatalyst by utilizing recycled newspaper as sustainable cellulose resource. Investigations on the influence of N-doped TiO2 nanorods incorporation on the structural and morphological properties of RC/N-TiO2 nanocomposite thin film are presented. The resulting nanocomposite thin film was characterized by FESEM, AFM, FTIR, UV-vis-NIR spectroscopy, and XPS analysis. The results suggested that there was a remarkable compatibility between cellulose and N-doped TiO2 nanorods anchored onto the surface of the RC/N-TiO2 nanocomposite thin film. Under UV and visible irradiation, the RC/N-TiO2 nanocomposite thin film showed remarkable photocatalytic activity for the degradation of methylene blue solution with degradation percentage of 96% and 78.8%, respectively. It is crucial to note that the resulting portable photocatalyst produced via an environmental and green technique in its fabrication process has good potential in the field of water and wastewater treatment application.

摘要

在这项工作中,通过利用回收报纸作为可持续的纤维素资源,设计了一种环保的 RC/N-TiO2 纳米复合材料薄膜,作为一种绿色便携式光催化剂。本研究探讨了掺杂 N 的 TiO2 纳米棒的掺入对 RC/N-TiO2 纳米复合材料薄膜结构和形态特性的影响。通过 FESEM、AFM、FTIR、UV-vis-NIR 光谱和 XPS 分析对所得纳米复合材料薄膜进行了表征。结果表明,纤维素与掺杂 N 的 TiO2 纳米棒之间具有显著的相容性,纳米棒锚定在 RC/N-TiO2 纳米复合材料薄膜的表面上。在 UV 和可见光照射下,RC/N-TiO2 纳米复合材料薄膜对亚甲基蓝溶液的降解具有显著的光催化活性,降解率分别为 96%和 78.8%。值得注意的是,通过环保绿色技术在其制备过程中生产的这种便携式光催化剂在水和废水处理应用领域具有良好的应用潜力。

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