Valtakari Dimitar, Liu Jun, Kumar Vinay, Xu Chunlin, Toivakka Martti, Saarinen Jarkko J
Laboratory of Paper Coating and Converting, Center for Functional Materials (FunMat), Abo Akademi University, Porthansgatan 3, 20500, Åbo/Turku, Finland.
Laboratory of Wood and Paper Chemistry, Abo Akademi University, Porthansgatan 3, 20500, Åbo/Turku, Finland.
Nanoscale Res Lett. 2015 Dec;10(1):386. doi: 10.1186/s11671-015-1093-y. Epub 2015 Oct 5.
Aqueous dispersion of conductive polymer poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (
PSS) was deposited on spin-coated and drop cast nanofibrillar cellulose (NFC)-glycerol (G) matrix on a glass substrate. A thin glycerol film was utilized on plasma-treated glass substrate to provide adequate adhesion for the NFC-glycerol (NFC-G) film. The effects of annealing temperature, the coating method of NFC-G, and the coating time intervals on the electrical performance of the
PSS were characterized.
PSS on drop cast NFC-G resulted in 3 orders of magnitude increase in the electrical conductivity compared to reference
PSS film on a reference glass substrate, whereas the optical transmission was only slightly decreased. The results point out the importance of the interaction between the
PSS and the NFC-G for the electrical and barrier properties for thin film electronics applications.
将导电聚合物聚(3,4 - 乙撑二氧噻吩)-聚(苯乙烯磺酸盐)(PEDOT:PSS)的水分散体沉积在玻璃基板上旋涂和滴铸的纳米纤维纤维素(NFC)-甘油(G)基质上。在经过等离子体处理的玻璃基板上使用薄甘油膜,为NFC - 甘油(NFC - G)膜提供足够的附着力。表征了退火温度、NFC - G的涂覆方法以及涂覆时间间隔对PEDOT:PSS电学性能的影响。与参考玻璃基板上的参考PEDOT:PSS膜相比,滴铸在NFC - G上的PEDOT:PSS的电导率提高了3个数量级,而光透射率仅略有下降。结果指出了PEDOT:PSS与NFC - G之间的相互作用对于薄膜电子应用的电学和阻隔性能的重要性。