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在水相环境中具有机械“熔丝链接”的可靠水凝胶。

Reliable Hydrogel with Mechanical "Fuse Link" in an Aqueous Environment.

机构信息

Department of Bioengineering, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.

Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan.

出版信息

Adv Mater. 2015 Dec 2;27(45):7407-11. doi: 10.1002/adma.201503130. Epub 2015 Oct 7.

DOI:10.1002/adma.201503130
PMID:26443000
Abstract

A robust hydrogel with a reliable deformation region in an aqueous environment is proposed. The gel has a homogeneous network where hydrophilic/hydrophobic components are uniformly distributed. In an aqueous environment, aggregated hydrophobic segments serve as "mechanical fuse links," inhibiting sudden macroscopic fracture. The gel endures threefold stretching for more than 100 cycles in water without mechanical hysteresis.

摘要

提出了一种在水介质中具有可靠变形区域的强韧水凝胶。该水凝胶具有均匀分布亲/疏水组分的均匀网络。在水介质中,聚集的疏水链段充当“机械熔丝键”,抑制突然的宏观断裂。该水凝胶在水中经受三倍拉伸超过 100 个循环而无力学滞后。

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