Hristov Delyan R, Mahon Eugene, Dawson Kenneth A
Center for BioNano Interactions, School of Chemsitry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland.
Chem Commun (Camb). 2015 Dec 21;51(98):17420-3. doi: 10.1039/c5cc06598d. Epub 2015 Oct 15.
We describe the control of size and homogeneity in silica nanoparticle dispersions, prepared by a two-phase arginine catalysed aqueous method, through varying the upper organic solvent phase. The final particle dispersion characteristics can be controlled by varying features including solvent type and interfacial area, related to the rate of monomer transfer at the TEOS/water interface.
我们描述了通过改变上层有机溶剂相,对采用双相精氨酸催化水相法制备的二氧化硅纳米颗粒分散体的尺寸和均匀性进行控制。最终颗粒分散体的特性可通过改变包括溶剂类型和界面面积等特征来控制,这些特征与正硅酸乙酯/水界面处单体转移速率有关。