Jordão Helga, Sousa António Jorge, Carvalho M Teresa
CERENA - Centro de Recursos Naturais e Ambiente, Avenida Rovisco Pais, 1049-001 Lisbon, Portugal.
Waste Manag. 2016 Feb;48:366-373. doi: 10.1016/j.wasman.2015.10.006. Epub 2015 Oct 23.
With the purpose of reducing the waste generated by end-of-life vehicles (ELVs) by enhancing the recovery and recycling of nonferrous metals, an experimental study was conducted with the finest size fraction of nonferrous stream produced at an ELV shredder plant. The aim of this work was to characterize the nonferrous stream and to evaluate the efficiency of a gravity concentration process in separating light and heavy nonferrous metal particles that could be easily integrated in a ELV shredder plant (in this case study the separation explicitly addressed copper and aluminum separation). The characterization of a sample of the 0-10mm particle size fraction showed a mixture of nonferrous metals with a certain degree of impurity due to the present of contaminants such as plastics. The majority of the particles exhibited a wire shape, preventing an efficient separation of materials without prior fragmentation. The gravity concentration process selected for this study was the wet shaking table and three operating parameters of the equipment were manipulated. A full factorial design in combination with a central composite design was employed to model metals recovery. Two second order polynomial equations were successfully fitted to describe the process and predict the recovery of copper and aluminum in Cu concentrate under the conditions of the present study. The optimum conditions were determined to be 11.1° of inclination, 2.8L/min of feed water flow and 4.9L/min of wash water flow. All three final products of the wet shaking table had a content higher than 90% in relation to one of the metals, wherein a Cu concentrate product was obtained with a Cu content of 96%, and 78% of Cu recovery and 2% of Al recovery.
为了通过加强有色金属的回收利用来减少报废汽车(ELV)产生的废物,对一家ELV破碎厂产生的最细粒度级分的有色金属流进行了实验研究。这项工作的目的是对有色金属流进行表征,并评估重力选矿工艺在分离轻、重有色金属颗粒方面的效率,这些颗粒可以很容易地整合到ELV破碎厂中(在本案例研究中,分离明确针对铜和铝的分离)。对0-10mm粒度级分的样品进行表征发现,由于存在塑料等污染物,有色金属混合物存在一定程度的杂质。大多数颗粒呈线状,在没有预先破碎的情况下无法有效地分离物料。本研究选择的重力选矿工艺是湿式摇床,并对该设备的三个操作参数进行了调整。采用全因子设计与中心复合设计相结合的方法对金属回收率进行建模。成功拟合了两个二阶多项式方程来描述该过程,并预测在本研究条件下铜精矿中铜和铝的回收率。确定最佳条件为倾斜度11.1°、给水流速2.8L/min和洗水流速4.9L/min。湿式摇床的所有三种最终产品中,其中一种金属的含量均高于90%,其中获得了铜含量为96%的铜精矿产品,铜回收率为78%,铝回收率为2%。