Fitzpatrick Anthony J, Trzop Elzbieta, Müller-Bunz Helge, Dîrtu Marinela M, Garcia Yann, Collet Eric, Morgan Grace G
School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland.
Institute of Condensed Matter and Nanosciences, Molecules, Solids and Reactivity (IMCN/MOST) Université Catholique de Louvain, Place L. Pasteur 1, 1348 Louvain-la-neuve, Belgium.
Chem Commun (Camb). 2015 Dec 25;51(99):17540-3. doi: 10.1039/c5cc05129k.
A symmetry breaking spin transition in a Mn(III) complex is reported with three structural phases, a high symmetry high temperature S = 2 phase, an intermediate S = 1/S = 2 ordered phase and an aperiodic low temperature phase with S = 1 cations. The aperiodicity is interpreted as resulting from long-range ordering of the NTf2(-) anions.
报道了一种锰（III）配合物中的对称破缺自旋转变，其具有三个结构相：一个高温高对称的S = 2相、一个中间的S = 1/S = 2有序相以及一个具有S = 1阳离子的非周期性低温相。这种非周期性被解释为NTf2(-)阴离子长程有序排列的结果。
