Muñiz Kilian
Institute of Chemical Research of Catalonia (ICIQ), 16 Avgda. Països Catalans, 43007, Tarragona, Spain.
Catalan Institution for Research and Advanced Studies (ICREA), Pg. Lluís Companys 23, 08010, Barcelona, Spain.
Top Curr Chem. 2016;373:105-33. doi: 10.1007/128_2015_663.
Recent progress in the area of hypervalent iodine-mediated and catalyzed amination reaction of hydrocarbons is reviewed. These reactions comprise processes under both intra and intermolecular control and include the functionalization of aromatic C-H bonds as well as conversion of sp-, sp(2)-, and sp(3)-hybridized carbon atoms. These developments demonstrate that hypervalent iodine(III) methodology has reached a high level in amination chemistry. The individual reactions are discussed with a focus on mechanistic details and emphasis is made to the underlying hypervalent iodine reagents, for which structural information is available.
综述了高价碘介导和催化的烃类胺化反应领域的最新进展。这些反应包括分子内和分子间控制下的过程，包括芳族C-H键的官能化以及sp-、sp(2)-和sp(3)-杂化碳原子的转化。这些进展表明，高价碘(III)方法在胺化化学中已达到很高水平。对各个反应进行了讨论，重点是机理细节，并强调了可获得结构信息的潜在高价碘试剂。
