高价碘（III）催化烯烃官能化的最新进展。
Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenes.
作者信息
Li Xiang, Chen Pinhong, Liu Guosheng
机构信息
State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.
出版信息
Beilstein J Org Chem. 2018 Jul 18;14:1813-1825. doi: 10.3762/bjoc.14.154. eCollection 2018.
Hypervalent iodine(III) reagents have been well-developed and widely utilized in functionalization of alkenes, however, generally either stoichiometric amounts of iodine(III) reagents are required or stoichiometric oxidants such as CPBA are employed to in situ generate iodine(III) species. In this review, recent developments of hypervalent iodine(III)-catalyzed functionalization of alkenes and asymmetric reactions using a chiral iodoarene are summarized.
高价碘（III）试剂已得到充分发展，并广泛应用于烯烃的官能团化反应中。然而，通常要么需要化学计量的碘（III）试剂，要么使用化学计量的氧化剂（如间氯过氧苯甲酸）原位生成碘（III）物种。在这篇综述中，总结了高价碘（III）催化的烯烃官能团化反应以及使用手性碘芳烃的不对称反应的最新进展。
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