Tai Yan-Long, Yang Zhen-Guo
Department of Materials Science, Fudan University , Shanghai 200433, China.
Physical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST) , Thuwal 23955-6900, Saudi Arabia.
Langmuir. 2015 Dec 8;31(48):13257-64. doi: 10.1021/acs.langmuir.5b03449. Epub 2015 Nov 20.
Flexible transparent conductive films (FTCFs) as the essential components of the next generation of functional circuits and devices are presently attracting more attention. Here, a new strategy has been demonstrated to fabricate thickness-controllable FTCFs through coffee ring lithography (CRL) of single-wall carbon nanotube (SWCNT)/poly(3,4-ethylenedioxythiophene)-polystyrenesulfonate (
PSS) hybrid ink. The influence of ink concentration and volume on the thickness and size of hybrid film has been investigated systematically. Results show that the final FTCFs present a high performance, including a homogeneous thickness of 60-65 nm, a sheet resistance of 1.8 kohm/sq, a visible/infrared-range transmittance (79%, PET = 90%), and a dynamic mechanical property (>1000 cycle, much better than ITO film), respectively, when SWCNT concentration is 0.2 mg/mL, ink volume is 0.4 μL, drying at room temperature. Moreover, the benefits of these kinds of FTCFs have been verified through a full transparent, flexible noncontact sensing panel (3 × 4 sensing pixels) and a flexible battery-free wireless sensor based on a humidity sensing mechanism, showing excellent human/machine interaction with high sensitivity, good stability, and fast response/recovery ability.
柔性透明导电薄膜(FTCFs)作为下一代功能电路和器件的关键组件,目前正吸引着越来越多的关注。在此,已展示出一种新策略,即通过对单壁碳纳米管(SWCNT)/聚(3,4 - 乙撑二氧噻吩)-聚苯乙烯磺酸盐(PEDOT:PSS)混合墨水进行咖啡环光刻(CRL)来制备厚度可控的FTCFs。系统研究了墨水浓度和体积对混合薄膜厚度和尺寸的影响。结果表明,当SWCNT浓度为0.2 mg/mL、墨水量为0.4 μL且在室温下干燥时,最终的FTCFs呈现出高性能,包括均匀厚度为60 - 65 nm、方阻为1.8 kohm/sq、可见/红外波段透过率(79%,PET = 90%)以及动态机械性能(>1000次循环,远优于ITO薄膜)。此外,通过一个全透明、柔性非接触传感面板(3×4传感像素)和一个基于湿度传感机制的柔性无电池无线传感器,验证了这类FTCFs的优势,其展现出优异的人机交互性能,具有高灵敏度、良好的稳定性以及快速的响应/恢复能力。