School of Public Health, Seoul National University, Seoul 08826, Republic of Korea.
School of Public Health, Seoul National University, Seoul 08826, Republic of Korea; Department of Environmental Engineering, Seoul National University of Science and Technology, Seoul 01811, Republic of Korea.
Sci Total Environ. 2016 Mar 15;547:441-446. doi: 10.1016/j.scitotenv.2015.12.135. Epub 2016 Jan 26.
Phthalates are important endocrine disrupting chemicals that have been linked to various adverse human health effects. Phthalates are ubiquitously present in indoor environment and could enter humans. Vinyl or PVC floorings have been recognized as one of important sources of phthalate release to indoor environment including house dust. In the present study, we estimated the migration of di(2-ethylhexyl)phthalate (DEHP) and di-isononyl phthalate (DINP) from the flooring materials into the dust under different heating conditions. For this purpose, a small chamber specifically designed for the present study and a Field and Laboratory Emission Cell (FLEC) were used, and four major types of PVC flooring samples including two UV curing paint coated, an uncoated residential, and a wax-coated commercial type were tested. Migration of DEHP was observed for an uncoated residential type and a wax-coated commercial type flooring. After 14 days of incubation, the levels of DEHP in the dust sample was determined at room temperature on average (standard deviation) at 384 ± 19 and 481 ± 53 μg/g, respectively. In contrast, migration of DINP was not observed. The migration of DEHP was strongly influenced by surface characteristics such as UV curing coating. In the residential flooring coated with UV curing paint, migration of DEHP was not observed at room temperature. But under the heated condition, the release of DEHP was observed in the dust in the FLEC. Migration of DEHP from flooring materials increased when the flooring was heated (50 °C). In Korea, heated flooring system, or 'ondol', is very common mode of heating in residential setting, therefore the contribution of PVC flooring to the total indoor DEHP exposure among general population is expected to be greater especially during winter season when the floor is heated.
邻苯二甲酸酯是重要的内分泌干扰化学物质,已被证实与多种人类健康不良影响有关。邻苯二甲酸酯广泛存在于室内环境中,并可能进入人体。乙烯基或 PVC 地板已被认为是向室内环境(包括室内灰尘)释放邻苯二甲酸酯的重要来源之一。在本研究中,我们评估了不同加热条件下地板材料中邻苯二甲酸二(2-乙基己基)酯(DEHP)和邻苯二甲酸二异壬酯(DINP)向灰尘中迁移的情况。为此,专门设计了一个小室和一个现场和实验室排放单元(FLEC),并测试了四种主要类型的 PVC 地板样品,包括两种紫外线固化涂料涂层、一种未涂层住宅地板和一种涂蜡商用地板。在未涂层住宅地板和涂蜡商用地板中观察到 DEHP 的迁移。经过 14 天的孵育,在室温下,灰尘样品中 DEHP 的含量分别平均(标准偏差)为 384 ± 19 和 481 ± 53 μg/g。相比之下,未观察到 DINP 的迁移。DEHP 的迁移强烈受到表面特性(如紫外线固化涂料)的影响。在住宅地板涂有紫外线固化涂料的情况下,在室温下未观察到 DEHP 的迁移。但在加热条件下,在 FLEC 中的灰尘中观察到 DEHP 的释放。当地板加热(50°C)时,地板材料中 DEHP 的迁移增加。在韩国,加热地板系统,或“ondol”,是住宅环境中非常常见的加热方式,因此 PVC 地板对普通人群总室内 DEHP 暴露的贡献预计会更大,尤其是在冬季地板加热时。