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利用厌氧氨氧化和反硝化作用去除氮素处理城市污水

[Nitrogen Removal Using ANAMMOX and Denitrification for Treatment of Municipal Sewage].

作者信息

Zhang Shi-ying, Wu Peng, Song Yin-ling, Shen Yao-liang, Zhang Ting

出版信息

Huan Jing Ke Xue. 2015 Nov;36(11):4174-9.

Abstract

In this study, an Anaerobic Baffled Reactor ( ABR) was constructed. The ANAMMOX process was successfully started up using this reactor within 45 days under the following condition: 27 degrees C, pH of 8, HRT of 10 h, and the influent NO2(-) -N/NH4(+) -N was 1.32. At the stable phase, the average TN removal percentages reached 83% and the ΔNH4(+) -N: ΔNO2(-) -N: ΔNO3(-) -N was 1 : 1. 31 : 0.27. In the process of treating municipal sewage, there was inevitably a certain amount of organic carbon in the influent. Organic carbon had no obvious effect on the ANAMMOX process at C/N of 0.5; Nitrogen removal was improved, and the average total nitrogen (TN, including ammonia, nitrite and nitrate nitrogen) removal efficiency of 93% was obtained at C/N of 1. However, at C/N of 2, the TN removal performance reduced due to the suppression of ANAMMOX by organic carbon; the ANAMMOX bacteria could recover their activity in a short period of time by reducing the influent COD concentration. In this work, the performance of the ANAMMOX-denitrification process in the treatment of municipal sewage was investigated, which proved the suitability of ABR-denitrification reactor in treating municipal sewage with low ammonia nitrogen concentration, with an effluent TN concentration of 7.5 mg x L(-1), and the average TN removal percentages reaching 86%.

摘要

在本研究中,构建了一个厌氧折流板反应器(ABR)。在27℃、pH值为8、水力停留时间(HRT)为10小时且进水NO2(-)-N/NH4(+)-N为1.32的条件下,利用该反应器在45天内成功启动了厌氧氨氧化过程。在稳定阶段,平均总氮(TN)去除率达到83%,ΔNH4(+)-N:ΔNO2(-)-N:ΔNO3(-)-N为1:1.31:0.27。在处理城市污水的过程中,进水不可避免地含有一定量的有机碳。当碳氮比(C/N)为0.5时,有机碳对厌氧氨氧化过程没有明显影响;当C/N为1时,脱氮效果得到改善,平均总氮(TN,包括氨氮、亚硝酸盐氮和硝酸盐氮)去除效率达到93%。然而,当C/N为2时,由于有机碳对厌氧氨氧化的抑制作用,TN去除性能降低;通过降低进水化学需氧量(COD)浓度,厌氧氨氧化细菌可以在短时间内恢复其活性。在本研究中,对厌氧氨氧化-反硝化过程处理城市污水的性能进行了研究,结果证明ABR-反硝化反应器适用于处理低氨氮浓度的城市污水,出水TN浓度为7.5mg·L(-1),平均TN去除率达到86%。

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