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生物质衍生醛糖的催化异构化：综述

Catalytic Isomerization of Biomass-Derived Aldoses: A Review.

作者信息

Delidovich Irina, Palkovits Regina

机构信息

Chair of Heterogeneous Catalysis and Chemical Technology, RWTH Aachen University, Worringerweg 2, 52074, Aachen, Germany.

出版信息

ChemSusChem. 2016 Mar 21;9(6):547-61. doi: 10.1002/cssc.201501577. Epub 2016 Mar 7.

DOI:10.1002/cssc.201501577
PMID:26948404
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5069572/
Abstract

Selected aldohexoses (D-glucose, D-mannose, and D-galactose) and aldopentoses (D-xylose, L-arabinose, and D-ribose) are readily available components of biopolymers. Isomerization reactions of these substances are very attractive as carbon-efficient processes to broaden the portfolio of abundant monosaccharides. This review focuses on the chemocatalytic isomerization of aldoses into the corresponding ketoses as well as epimerization of aldoses at C2. Recent advances in the fields of catalysis by bases and Lewis acids are considered. The emphasis is laid on newly uncovered catalytic systems and mechanisms of carbohydrate transformations.

摘要

选定的己醛糖（D-葡萄糖、D-甘露糖和D-半乳糖）和戊醛糖（D-木糖、L-阿拉伯糖和D-核糖）是生物聚合物中容易获得的成分。这些物质的异构化反应作为一种碳高效的过程，用于拓宽丰富单糖的种类，极具吸引力。本综述重点关注醛糖化学催化异构化为相应的酮糖以及醛糖在C2位的差向异构化。文中考虑了碱催化和路易斯酸催化领域的最新进展。重点在于新发现的碳水化合物转化催化体系和机制。

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