Sharmah Gautam Krishna, Birman Vladimir B
Washington University , Department of Chemistry, Campus Box 1134, One Brookings Drive, Saint Louis, Missouri 63130, United States.
Org Lett. 2016 Apr 1;18(7):1499-501. doi: 10.1021/acs.orglett.5b03212. Epub 2016 Mar 14.
A concise stereo- and enantioselective synthesis of lingzhiol has been achieved featuring a biogenetically inspired Brønsted acid catalyzed semipinacol rearrangement of a glycidyl alcohol intermediate.
通过以生物合成灵感为导向、利用布朗斯特酸催化缩水甘油醇中间体的半频哪醇重排，实现了灵芝醇的简洁立体选择性和对映选择性合成。
