Wang Yunzhu, De Sudipta, Yan Ning
Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585, Singapore.
Chem Commun (Camb). 2016 May 7;52(37):6210-24. doi: 10.1039/c6cc00336b. Epub 2016 Mar 29.
Nano-scale metal particles have huge potential due to their wide range of diverse catalytic applications. Recently, they have found numerous applications in the field of biomass conversion. The proposed contribution is aimed at providing a brief account of remarkable recent findings and advances in the design of metal-based nanocatalysts for biomass valorization. We have discussed the rational control of the size, shape, composition and surface properties of nano-scale metal catalysts. Following that, the interplay between various structural parameters and the catalytic properties in the transformation of cellulose, chitin, lignin and lipids has been critically discussed.
纳米级金属颗粒因其广泛多样的催化应用而具有巨大潜力。最近,它们在生物质转化领域已得到众多应用。本文旨在简要介绍金属基纳米催化剂用于生物质增值设计方面近期的显著发现和进展。我们讨论了纳米级金属催化剂尺寸、形状、组成和表面性质的合理控制。在此之后,还对纤维素、几丁质、木质素和脂质转化过程中各种结构参数与催化性能之间的相互作用进行了批判性讨论。