Department of Applied Chemistry, Tokyo University of Agriculture & Technology, 2-24-16 Naka-cho, Koganei, Tokyo, 184-8558, Japan.
Division of Art and Innovative Technologies, K & W Inc., 1-3-16-901 Higashi, Kunitachi, Tokyo, 186-0002, Japan.
Adv Mater. 2016 Aug;28(31):6751-7. doi: 10.1002/adma.201600798. Epub 2016 May 27.
Anisotropically grown (b-axis short) single-nano TiO2 (B), uniformly hyper-dispersed on the surface of multiwalled carbon nanotubes (MWCNT), was successfully synthesized via an in situ ultracentrifugation (UC) process coupled with a follow-up hydrothermal treatment. The uc-TiO2 (B)/MWCNT composite materials enable ultrafast Li(+) intercalation especially along the b-axis, resulting in a capacity of 235 mA h g(-1) per TiO2 (B) even at 300C (1C = 335 mA g(-1) ).
通过原位超离心(UC)过程与后续水热处理相结合,成功合成了沿 b 轴(b 轴短)各向异性生长的单纳米 TiO2(B)均匀超分散在多壁碳纳米管(MWCNT)表面上。uc-TiO2(B)/MWCNT 复合材料能够实现超快 Li(+)嵌入,特别是沿 b 轴,即使在 300°C(1C=335 mA g(-1))下,TiO2(B)的容量也达到 235 mA h g(-1)。