Mendis Shehani N, Tunge Jon A
Department of Chemistry, The University of Kansas, 2010 Malott Hall, Lawrence, KS 66045, USA.
Chem Commun (Camb). 2016 Jun 8;52(49):7695-8. doi: 10.1039/c6cc03672d.
We report the first example of a palladium-catalyzed decarboxylative dearomatization reaction that occurs via Pd-π-benzyl intermediates. In fact, the Pd-catalyzed decarboxylative cross-coupling reaction of benzyl enol carbonates can lead to either the dearomatized alicyclic ketones or α-monoarylated ketone products depending on the catalyst and ligand employed.
我们报道了首例通过钯-π-苄基中间体发生的钯催化脱羧去芳构化反应。事实上，苄基烯醇碳酸酯的钯催化脱羧交叉偶联反应根据所使用的催化剂和配体的不同，可生成去芳构化的脂环族酮或α-单芳基化酮产物。
