通过钯催化的3-氧代羧酸脱羧烯丙基化反应合成3,4-二烯基酮
3,4-Alkadienyl ketones via the palladium-catalyzed decarboxylative allenylation of 3-oxocarboxylic acids.
作者信息
Zhu Tonghao, Ma Shengming
机构信息
Department of Chemistry, Fudan University, 220 Handan Lu, Shanghai 200433, P. R. China.
出版信息
Chem Commun (Camb). 2017 May 30;53(44):6037-6040. doi: 10.1039/c7cc02050c.
PMID:28524922
Abstract
In this communication, we report a palladium-catalyzed decarboxylative allenylation of benzyl carbonates and tert-butyl carbonates of 2,3-allenols with 3-oxocarboxylic acids. The reaction provides a new and straightforward approach to 3,4-dienyl ketones under mild conditions.
摘要
在本通讯中，我们报道了钯催化2,3-联烯醇的碳酸苄酯和碳酸叔丁酯与3-氧代羧酸的脱羧烯丙基化反应。该反应在温和条件下为3,4-二烯基酮提供了一种新颖且直接的合成方法。
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