Department of Chemistry, University of California , Berkeley, California 94720, United States.
ACS Cent Sci. 2016 May 25;2(5):293-301. doi: 10.1021/acscentsci.6b00090. Epub 2016 May 3.
Since initial reports, cross-coupling technologies employing photoredox catalysts to access novel reactivity have developed with increasing pace. In this Outlook, prominent examples from the recent literature are organized on the basis of the elementary transformation enabled by photoredox catalysis and are discussed in the context of relevant historical precedent in stoichiometric organometallic chemistry. This treatment allows mechanistic similarities inherent to odd-electron transition metal reactivity to be generalized to a set of lessons for future reaction development.
自最初的报道以来，采用光氧化还原催化剂来获得新反应性的交叉偶联技术发展迅速。在本展望中，根据光氧化还原催化所实现的基本转化，对近期文献中的突出实例进行了组织，并结合相关的化学计量有机金属化学的历史先例进行了讨论。这种处理方法可以将奇数电子过渡金属反应性所固有的机理相似性推广到一组未来反应开发的经验教训。
