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控制协同氧化过程以实现高效稳定的蓝色热激活延迟荧光器件。

Controlling Synergistic Oxidation Processes for Efficient and Stable Blue Thermally Activated Delayed Fluorescence Devices.

机构信息

Center for Organic Photonics and Electronics Research (OPERA), Kyushu University, Fukuoka, 819-0395, Japan.

Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM) and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, 215123, P. R. China.

出版信息

Adv Mater. 2016 Sep;28(35):7620-5. doi: 10.1002/adma.201602127. Epub 2016 Jun 23.

Abstract

Efficient sky-blue organic light-emitting diodes (OLEDs) employing thermally activated delayed fluorescence (TADF) display a three orders of magnitude increase in lifetime, which is superior to those of controlled phosphorescent OLEDs used in this study. The combination of electro-oxidation and photo-oxidation of the TADF emitters in their triplet excited-states is suppressed through molecule design and device engineering.

摘要

高效天蓝光致发光二极管(OLED)采用热激活延迟荧光(TADF)技术,寿命延长了三个数量级,优于本研究中使用的受控磷光 OLED。通过分子设计和器件工程抑制了 TADF 发射器三重态激发态的电氧化和光氧化的结合。

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