Jeon Sang Kyu, Lee Ha Lim, Yook Kyoung Soo, Lee Jun Yeob
School of Chemical Engineering, Sungkyunkwan University, 2066 Seobu-ro, Jangan-gu, Suwon-si, Gyeonggi-do, 446-740, South Korea.
Adv Mater. 2019 Aug;31(34):e1803524. doi: 10.1002/adma.201803524. Epub 2019 Mar 25.
Recently, the external quantum efficiency and lifetime of organic light-emitting diodes (OLEDs) have been dramatically upgraded due to development of organic materials and device structure. In particular, an intramolecular or intermolecular complex based on thermally activated delayed fluorescent (TADF) materials has greatly contributed to improving OLED device performance. Although high external quantum efficiency has been the main objective of the development of TADF materials as hosts and emitters, recent interest has been directed towards the lifetime of TADF-material-based OLEDs. For the past several years, remarkable advances in the lifetime of phosphorescent and TADF OLEDs have been made using TADF materials as hosts or emitters in the emitting layer. Therefore, since TADF materials are useful as both hosts and emitters for a long lifetime, this work discusses the recent progress made in developing TADF materials for long-lifetime OLEDs.
近年来,由于有机材料和器件结构的发展,有机发光二极管(OLED)的外量子效率和寿命得到了显著提升。特别是,基于热激活延迟荧光(TADF)材料的分子内或分子间复合物对提高OLED器件性能做出了巨大贡献。尽管高外量子效率一直是TADF材料作为主体和发光体发展的主要目标,但最近人们的兴趣已转向基于TADF材料的OLED的寿命。在过去几年中,通过在发光层中使用TADF材料作为主体或发光体,磷光和TADF OLED的寿命取得了显著进展。因此,由于TADF材料作为主体和发光体都有助于实现长寿命,本文讨论了在开发用于长寿命OLED的TADF材料方面取得的最新进展。