Preferential Isomer Formation Observed in H + CO by Crossed Beam Imaging.

The proton transfer reaction H3(+) + CO is one of the cornerstone chemical processes in the interstellar medium. Here, the dynamics of this reaction have been investigated using crossed beam velocity map imaging. Formyl product cations are found to be predominantly scattered into the forward direction irrespective of the collision energy. In this process, a high amount of energy is transferred to internal product excitation. By fitting a sum of two distribution functions to the measured internal energy distributions, the product isomer ratio is extracted. A small HOC(+) fraction is obtained at a collision energy of 1.8 eV, characterized by an upper limit of 24% with a confidence level of 84%. At lower collision energies, the data indicate purely HCO(+) formation. Such low values are unexpected given the previously predicted efficient formation of both HCO(+) and HOC(+) isomers for thermal conditions. This is discussed in light of the direct reaction dynamics that are observed.