• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

铜的X射线光谱分析：一个老课题的新成果

X-Ray Spectrometry of Copper: New Results on an Old Subject.

作者信息

Deutsch M, Förster E, Hölzer G, Härtwig J, Hämäläinen K, Kao C-C, Huotari S, Diamant R

机构信息

Physics Dept., Bar-Ilan University, Ramat-Gann 52900, Israel.

Institute for Optics and Quantum Electronics, Friedrich-Schiller-University Jena, D-07743 Jena, Germany.

出版信息

J Res Natl Inst Stand Technol. 2004 Feb 1;109(1):75-98. doi: 10.6028/jres.109.006. Print 2004 Jan-Feb.

DOI:10.6028/jres.109.006
PMID:27366598
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4849622/
Abstract

We review recent, and some less recent, measurements of several emission spectra of copper. The results are discussed with special emphasis on elucidating the structure of the Kα 1,2 and Kβ 1,3 diagram lines and their underlying transitions. These lines are found to contain ≈30 % contribution from 3d spectator hole transitions. Other multielectronic transitions, the 2p spectator hole (satellites) and 1s spectator hole (hypersatellites) transitions were also measured. They are discussed paying special attention to the evolution of the lineshapes and intensities from the excitation threshold to saturation. Trends in the measured quantities depending on the spectator hole's shell and subshell are also discussed.

摘要

我们回顾了近期以及一些稍早时期对铜的几种发射光谱的测量结果。讨论这些结果时特别强调了阐明Kα 1,2和Kβ 1,3标识谱线的结构及其潜在跃迁。发现这些谱线中约30%的贡献来自3d旁观空穴跃迁。还测量了其他多电子跃迁，即2p旁观空穴（卫星峰）和1s旁观空穴（超卫星峰）跃迁。讨论这些跃迁时特别关注了从激发阈值到饱和状态下谱线形状和强度的演变。还讨论了测量量随旁观空穴所在壳层和子壳层变化的趋势。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/ace011193853/j91deuf16.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/2d5c92f1c409/j91deuf1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/1e529fdfe5a4/j91deuf2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/4c78d999c7ff/j91deuf3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/57c317eebd79/j91deuf4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/407e39dddad1/j91deuf5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/b4e1a1902f3d/j91deuf6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/188d97bb9632/j91deuf7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/24863b6bec53/j91deuf8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/86480b99e049/j91deuf9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/b6a1538dd31b/j91deuf10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/7c206a3f9f30/j91deuf11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/baab4fea4acc/j91deuf12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/a223d844969b/j91deuf13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/f17b10ec3c18/j91deuf14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/a2c4dc404668/j91deuf15.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/ace011193853/j91deuf16.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/2d5c92f1c409/j91deuf1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/1e529fdfe5a4/j91deuf2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/4c78d999c7ff/j91deuf3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/57c317eebd79/j91deuf4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/407e39dddad1/j91deuf5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/b4e1a1902f3d/j91deuf6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/188d97bb9632/j91deuf7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/24863b6bec53/j91deuf8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/86480b99e049/j91deuf9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/b6a1538dd31b/j91deuf10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/7c206a3f9f30/j91deuf11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/baab4fea4acc/j91deuf12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/a223d844969b/j91deuf13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/f17b10ec3c18/j91deuf14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/a2c4dc404668/j91deuf15.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/189a/4849622/ace011193853/j91deuf16.jpg

相似文献

1
X-Ray Spectrometry of Copper: New Results on an Old Subject.铜的X射线光谱分析：一个老课题的新成果
J Res Natl Inst Stand Technol. 2004 Feb 1;109(1):75-98. doi: 10.6028/jres.109.006. Print 2004 Jan-Feb.
2
Ab Initio Manganese K and K Energy Eigenvalues, Shake-Off Probabilities, Auger Rates, with Convergence Tests.从头算锰的K和K'能量本征值、振激概率、俄歇速率及收敛性测试
Molecules. 2024 Sep 4;29(17):4199. doi: 10.3390/molecules29174199.
3
Diagram X-ray emission spectra of a hollow atom: the Kh alpha1,2 and Kh beta1,3 hypersatellites of Fe.空心原子的X射线发射光谱图：铁的Kα1,2和Kβ1,3超卫星峰
Phys Rev Lett. 2003 Nov 7;91(19):193001. doi: 10.1103/PhysRevLett.91.193001. Epub 2003 Nov 6.
4
Observation of Seeded Mn Kβ Stimulated X-Ray Emission Using Two-Color X-Ray Free-Electron Laser Pulses.利用双色X射线自由电子激光脉冲对种子注入锰Kβ受激X射线发射的观测
Phys Rev Lett. 2020 Jul 17;125(3):037404. doi: 10.1103/PhysRevLett.125.037404.
5
Intensity Ratio of / in Selected Elements from Mg to Cu, and the Chemical Effects of Cr Diagram Lines and Cr / Intensity Ratio in Cr Compounds.从镁到铜的选定元素的强度比，以及铬谱线的化学效应和铬化合物中铬/强度比。
Int J Mol Sci. 2023 Mar 14;24(6):5570. doi: 10.3390/ijms24065570.
6
Kβ X-ray Emission Spectroscopy as a Probe of Cu(I) Sites: Application to the Cu(I) Site in Preprocessed Galactose Oxidase.Kβ X 射线发射光谱法作为探测 Cu(I)位点的探针：在预处理半乳糖氧化酶中 Cu(I)位点的应用。
Inorg Chem. 2020 Nov 16;59(22):16567-16581. doi: 10.1021/acs.inorgchem.0c02495. Epub 2020 Nov 2.
7
Chemical Sensitivity of Kβ and Kα X-ray Emission from a Systematic Investigation of Iron Compounds.铁化合物系统研究的 Kβ 和 Kα X 射线发射的化学敏感性。
Inorg Chem. 2020 Sep 8;59(17):12518-12535. doi: 10.1021/acs.inorgchem.0c01620. Epub 2020 Aug 24.
8
Chemical State Analysis of Phosphorus Performed by X-ray Emission Spectroscopy.用X射线发射光谱法进行的磷的化学态分析
Anal Chem. 2015 Jun 2;87(11):5632-9. doi: 10.1021/acs.analchem.5b00782. Epub 2015 May 14.
9
Evolution from threshold of a hollow Atom's X-Ray emission spectrum: the Cu k(h)alpha(1,2) hypersatellites.
Phys Rev Lett. 2000 Apr 10;84(15):3278-81. doi: 10.1103/PhysRevLett.84.3278.
10
Effect of external magnetic field on the Kβ/Kα X-ray intensity ratios of TixNi1-x alloys excited by 59.54 and 22.69keV photons.外部磁场对由59.54keV和22.69keV光子激发的TixNi1-x合金的Kβ/Kα X射线强度比的影响。
Appl Radiat Isot. 2016 Sep;115:183-189. doi: 10.1016/j.apradiso.2016.06.026. Epub 2016 Jun 22.

引用本文的文献

1
The NIST Vacuum Double-Crystal Spectrometer: A Tool for SI-Traceable Measurement of X-Ray Emission Spectra.美国国家标准与技术研究院真空双晶光谱仪：一种用于对X射线发射光谱进行可溯源至国际单位制测量的工具。
J Res Natl Inst Stand Technol. 2022 Mar 9;126:126049. doi: 10.6028/jres.126.049. eCollection 2021.
2
Absolute energies and emission line shapes of the L x-ray transitions of lanthanide metals.镧系金属L X射线跃迁的绝对能量和发射线形状。
Metrologia. 2021 Feb;58(1). doi: 10.1088/1681-7575/abd28a.
3
Kβ X-ray Emission Spectroscopy as a Probe of Cu(I) Sites: Application to the Cu(I) Site in Preprocessed Galactose Oxidase.

本文引用的文献

1
CODATA recommended values of the fundamental physical constants: 2018.国际科学技术数据委员会（CODATA）推荐的基本物理常数数值：2018年版
Rev Mod Phys. 2021 Apr-Jun;93(2). doi: 10.1103/RevModPhys.93.025010. Epub 2021 Jun 30.
2
Evolution from threshold of a hollow Atom's X-Ray emission spectrum: the Cu k(h)alpha(1,2) hypersatellites.
Phys Rev Lett. 2000 Apr 10;84(15):3278-81. doi: 10.1103/PhysRevLett.84.3278.
3
Onset and near threshold evolution of the Cu K alpha x-ray satellites.铜Kα X射线卫星峰的起始与近阈值演化
Kβ X 射线发射光谱法作为探测 Cu(I)位点的探针：在预处理半乳糖氧化酶中 Cu(I)位点的应用。
Inorg Chem. 2020 Nov 16;59(22):16567-16581. doi: 10.1021/acs.inorgchem.0c02495. Epub 2020 Nov 2.
4
Equatorial aberration of powder diffraction data collected with an Si strip X-ray detector by a continuous-scan integration method.采用连续扫描积分法，用硅条X射线探测器收集粉末衍射数据时的赤道像差。
J Appl Crystallogr. 2020 May 5;53(Pt 3):679-685. doi: 10.1107/S1600576720005130. eCollection 2020 Jun 1.
5
High x-ray resolving power utilizing asymmetric diffraction from a quartz transmission crystal measured in the 6  keV to 22  keV energy range.在6千电子伏特至22千电子伏特能量范围内，利用石英透射晶体的非对称衍射实现了高X射线分辨能力。
Appl Opt. 2019 Jul 1;58(19):5225-5232. doi: 10.1364/AO.58.005225.
6
Incorporation of osteopontin peptide into kidney stone-related calcium oxalate monohydrate crystals: a quantitative study.将骨桥蛋白肽纳入肾结石相关一水合草酸钙晶体中：一项定量研究。
Urolithiasis. 2019 Oct;47(5):425-440. doi: 10.1007/s00240-018-01105-x. Epub 2018 Dec 19.
7
X-ray spectrometer having 12 000 resolving power at 8 keV energy.在8keV能量下具有12000分辨能力的X射线光谱仪。
Rev Sci Instrum. 2017 Oct;88(10):103107. doi: 10.1063/1.4999995.
8
High-precision measurement of the X-ray Cu K spectrum.X射线铜K光谱的高精度测量。
J Phys B At Mol Opt Phys. 2017 Jun;50(11). doi: 10.1088/1361-6455/aa6c4a. Epub 2017 May 12.
Phys Rev Lett. 1996 Apr 1;76(14):2424-2427. doi: 10.1103/PhysRevLett.76.2424.
4
Evidence for a quadrupolar excitation channel at the LIII edge of gadolinium by resonant inelastic x-ray scattering.
Phys Rev Lett. 1995 Jun 12;74(24):4931-4934. doi: 10.1103/PhysRevLett.74.4931.
5
Elimination of the inner-shell lifetime broadening in x-ray-absorption spectroscopy.消除X射线吸收光谱中的内壳层寿命展宽。
Phys Rev Lett. 1991 Nov 11;67(20):2850-2853. doi: 10.1103/PhysRevLett.67.2850.
6
Correspondence of electron spectra from photoionization and nuclear internal conversion.
Phys Rev Lett. 1991 Oct 21;67(17):2291-2294. doi: 10.1103/PhysRevLett.67.2291.
7
Briand et al. reply.布莱恩等人回复。
Phys Rev Lett. 1990 Jul 9;65(2):269. doi: 10.1103/PhysRevLett.65.269.
8
Near-threshold resonance enhancement of neon valence satellites studied with synchrotron radiation.利用同步辐射研究氖价层卫星峰的近阈值共振增强
Phys Rev Lett. 1986 Mar 17;56(11):1120-1123. doi: 10.1103/PhysRevLett.56.1120.
9
L2,3 and M2,3 level widths and fluorescence yields of copper.铜的L2,3和M2,3能级宽度及荧光产率
Phys Rev A. 1995 Nov;52(5):3661-3668. doi: 10.1103/physreva.52.3661.
10
K alpha and K beta x-ray emission spectra of copper.铜的Kα和KβX射线发射光谱。
Phys Rev A. 1995 Jan;51(1):283-296. doi: 10.1103/physreva.51.283.