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通过正向渗透-反渗透(FO-RO)混合技术高效结合水的回用与海水淡化:一篇批判性综述

Efficiently Combining Water Reuse and Desalination through Forward Osmosis-Reverse Osmosis (FO-RO) Hybrids: A Critical Review.

作者信息

Blandin Gaetan, Verliefde Arne R D, Comas Joaquim, Rodriguez-Roda Ignasi, Le-Clech Pierre

机构信息

LEQUIA, Institute of the environment, University of Girona, Campus Montilivi, Girona 17003, Spain.

Department of Applied Analytical and Physical Chemistry, Ghent University, Faculty of Bioscience Engineering, Particle and Interfacial Technology Group (PaInT), Gent 9000, Belgium.

出版信息

Membranes (Basel). 2016 Jul 1;6(3):37. doi: 10.3390/membranes6030037.

Abstract

Forward osmosis (FO) is a promising membrane technology to combine seawater desalination and water reuse. More specifically, in a FO-reverse osmosis (RO) hybrid process, high quality water recovered from the wastewater stream is used to dilute seawater before RO treatment. As such, lower desalination energy needs and/or water augmentation can be obtained while delivering safe water for direct potable reuse thanks to the double dense membrane barrier protection. Typically, FO-RO hybrid can be a credible alternative to new desalination facilities or to implementation of stand-alone water reuse schemes. However, apart from the societal (public perception of water reuse for potable application) and water management challenges (proximity of wastewater and desalination plants), FO-RO hybrid has to overcome technical limitation such as low FO permeation flux to become economically attractive. Recent developments (i.e., improved FO membranes, use of pressure assisted osmosis, PAO) demonstrated significant improvement in water flux. However, flux improvement is associated with drawbacks, such as increased fouling behaviour, lower rejection of trace organic compounds (TrOCs) in PAO operation, and limitation in FO membrane mechanical resistance, which need to be better considered. To support successful implementation of FO-RO hybrid in the industry, further work is required regarding up-scaling to apprehend full-scale challenges in term of mass transfer limitation, pressure drop, fouling and cleaning strategies on a module scale. In addition, refined economics assessment is expected to integrate fouling and other maintenance costs/savings of the FO/PAO-RO hybrid systems, as well as cost savings from any treatment step avoided in the water recycling.

摘要

正向渗透(FO)是一种很有前景的膜技术,可用于海水淡化和水的再利用相结合。更具体地说,在正向渗透-反渗透(RO)混合工艺中,从废水流中回收的高质量水用于在RO处理之前稀释海水。这样一来,由于双重致密膜屏障保护,在提供安全的直接饮用水再利用水的同时,可以降低脱盐能源需求和/或增加水量。通常,FO-RO混合工艺可以成为新的海水淡化设施或单独实施水再利用方案的可靠替代方案。然而,除了社会方面(公众对饮用水应用中水再利用的认知)和水管理挑战(废水处理厂和海水淡化厂的距离)之外,FO-RO混合工艺还必须克服技术限制,例如低正向渗透通量,才能在经济上具有吸引力。最近的进展(即改进的正向渗透膜、压力辅助渗透PAO的使用)表明水通量有了显著提高。然而,通量的提高也伴随着一些缺点,如结垢行为增加、PAO运行中对痕量有机化合物(TrOCs)的截留率降低以及正向渗透膜机械阻力的限制,这些都需要更好地加以考虑。为了支持FO-RO混合工艺在工业中的成功实施,需要进一步开展工作,扩大规模以了解在模块规模上的传质限制、压降、结垢和清洗策略等全尺寸挑战。此外,预计完善的经济评估将整合FO/PAO-RO混合系统的结垢和其他维护成本/节省情况,以及水循环中避免的任何处理步骤所节省的成本。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5d1b/5041028/789a18e246e5/membranes-06-00037-g001.jpg

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