Shang Xiaojie, Liu Zhong-Quan
College of Resources and Environment, Gansu Agricultural University, Lanzhou, Gansu 730070, P. R. China.
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, Gansu 730000, P. R. China.
Org Biomol Chem. 2016 Aug 16;14(33):7829-31. doi: 10.1039/c6ob00797j.
As important and valuable alternatives to transition-metal-catalysis, free-radical strategies for C-Si bond construction via selective C-H/Si-H functionalization have been developed recently. These new reactions along with their suggested mechanisms are summarized and discussed here.
作为过渡金属催化的重要且有价值的替代方法，通过选择性C-H/Si-H官能化构建C-Si键的自由基策略最近已得到发展。本文总结并讨论了这些新反应及其提出的机理。
