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氧化石墨烯/甲阶酚醛树脂复合材料作为超级电容器应用电极材料的电化学性质

Electrochemical Properties of Graphene Oxide/Resol Composites as Electrode Materials for Supercapacitor Applications.

作者信息

Park Geon Woo, Jeon Sang Kwon, Yang Jin Yong, Choi Sung Dae, Kim Geon Joong

出版信息

J Nanosci Nanotechnol. 2016 May;16(5):4320-7. doi: 10.1166/jnn.2016.11016.

Abstract

RGO/Resol carbon composites were prepared from a mixture of reduced GO and a low-molecular-weight phenolic resin (Resol) solution. The effects of the calcination temperature, amount of Resol added and KOH treatment on the electrochemical performance of the RGO/Resol composites were investigated. The physical and electrochemical properties of the composite materials were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Brunauer, Emmett and Teller (BET) surface areas measurements, and cyclic voltammetry (CV). The relationships between their physical properties and their electrochemical performance were examined for use as super-capacitors (SCs). The RGO/Resol composite calcined at 400 degrees C after the KOH loading showed dramatically improved electrochemical properties, showing a high BET surface and capacitance of 2190 m2/g and 220 F/g, respectively. The RGO/Resol composites calcined after the KOH treatment showed much better capacitor performance than those treated only thermally at the same temperature without KOH impregnation. The fabrication of high surface electrodes was essential for improving the SCs properties.

摘要

通过还原氧化石墨烯(RGO)与低分子量酚醛树脂(甲阶酚醛树脂)溶液的混合物制备了RGO/甲阶酚醛树脂碳复合材料。研究了煅烧温度、甲阶酚醛树脂添加量和氢氧化钾处理对RGO/甲阶酚醛树脂复合材料电化学性能的影响。通过扫描电子显微镜(SEM)、X射线衍射(XRD)、布鲁诺尔-埃米特-泰勒(BET)比表面积测量和循环伏安法(CV)对复合材料的物理和电化学性能进行了表征。研究了它们的物理性能与用作超级电容器(SCs)的电化学性能之间的关系。在负载氢氧化钾后于400℃煅烧的RGO/甲阶酚醛树脂复合材料表现出显著改善的电化学性能,分别具有2190 m2/g的高BET比表面积和220 F/g的电容。经氢氧化钾处理后煅烧的RGO/甲阶酚醛树脂复合材料比在相同温度下仅进行热处理而未进行氢氧化钾浸渍的复合材料表现出更好的电容器性能。制备高比表面积电极对于改善超级电容器性能至关重要。

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