State Key Laboratory for Artificial Microstructure and Microscopic Physics, School of Physics, Peking University , Beijing 100871, China.
Department of Materials Science and Engineering, University of California ,Los Angeles, California 90095, United States.
ACS Appl Mater Interfaces. 2016 Aug 24;8(33):21480-9. doi: 10.1021/acsami.6b07044. Epub 2016 Aug 15.
The existence of high threading dislocation density (TDD) in GaN-based epilayers is a long unsolved problem, which hinders further applications of defect-sensitive GaN-based devices. Multiple-modulation of epitaxial lateral overgrowth (ELOG) is used to achieve high-quality GaN template on a novel serpentine channel patterned sapphire substrate (SCPSS). The dislocation blocking brought by the serpentine channel patterned mask, coupled with repeated dislocation bending, can reduce the dislocation density to a yet-to-be-optimized level of ∼2 × 10(5) to 2 × 10(6) cm(-2). About 80% area utilization rate of GaN with low TDD and stress relaxation is obtained. The periodical variations of dislocation density, optical properties and residual stress in GaN-based epilayers on SCPSS are analyzed. The quantum efficiency of InGaN/GaN multiple quantum wells (MQWs) on it can be increased by 52% compared with the conventional sapphire substrate. The reduced nonradiative recombination centers, the enhanced carrier localization, and the suppressed quantum confined Stark effect, are the main determinants of improved luminous performance in MQWs on SCPSS. This developed ELOG on serpentine shaped mask needs no interruption and regrowth, which can be a promising candidate for the heteroepitaxy of semipolar/nonpolar GaN and GaAs with high quality.
在 GaN 基外延层中存在高的位错密度(TDD)是一个长期未解决的问题,这阻碍了对缺陷敏感的 GaN 基器件的进一步应用。外延横向过生长(ELOG)的多重调制用于在新型蛇形通道图案化蓝宝石衬底(SCPSS)上实现高质量 GaN 模板。蛇形通道图案掩模带来的位错阻挡,加上反复的位错弯曲,可以将位错密度降低到尚未优化的水平,约为 2×10(5)到 2×10(6)cm(-2)。获得了具有低 TDD 和应力松弛的 GaN 的约 80%面积利用率。分析了 SCPSS 上 GaN 基外延层中位错密度、光学性质和残余应力的周期性变化。与传统蓝宝石衬底相比,它上面的 InGaN/GaN 多量子阱(MQWs)的量子效率可以提高 52%。减少非辐射复合中心、增强载流子局域化和抑制量子限制斯塔克效应是提高 SCPSS 上 MQWs 发光性能的主要决定因素。这种在蛇形掩模上开发的 ELOG 不需要中断和再生长,它可能是高质量的半极性/非极性 GaN 和 GaAs 异质外延的有前途的候选者。