Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Catedrático José Beltrán 2, 46980, Paterna, Valencia, Spain.
Departamento de Física Aplicada y Electromagnetismo, Universitat de Valencia, C/Dr. Moliner 50, Burjassot, Valencia, 46100, Spain.
Small. 2016 Oct;12(38):5245-5250. doi: 10.1002/smll.201600209. Epub 2016 Aug 24.
CH NH PbBr perovskite nanoparticles (P ) are prepared with a photoluminescence quantum yield of ≈100% in air atmosphere by using the quasi-spherical shaped 2-adamantylammonium bromide (ADBr) as the only capping ligand. The photostability under wet conditions of this kind of nanoparticles is enhanced by using cucurbit[7]uril-adamantylammonium (AD@CB) host-guest complexes as the capping ligand.
CH NH PbBr 钙钛矿纳米粒子(P)通过使用准球形的 2-金刚烷基溴化铵(ADBr)作为唯一的封端配体,在空气气氛中以约 100%的光致发光量子产率制备。通过使用葫芦[7]脲-金刚烷基铵(AD@CB)主客体配合物作为封端配体,这种纳米粒子在潮湿条件下的光稳定性得到增强。