• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

Synthesis of Trifluoromethylthiolated Alkenes and Ketones by Decarboxylative Functionalization of Cinnamic Acids.

作者信息

Pan Shen, Huang Yangen, Qing Feng-Ling

机构信息

College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, 2999 North Renmin Road, Shanghai, 201620, China.

Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 345 Lingling Road, Shanghai, 200032, China.

出版信息

Chem Asian J. 2016 Oct 20;11(20):2854-2858. doi: 10.1002/asia.201601098. Epub 2016 Sep 15.

DOI:10.1002/asia.201601098
PMID:27558971
Abstract

A tunable decarboxylative trifluoromethylthiolation of cinnamic acids with AgSCF was developed to afford trifluoromethylthiolated alkenes or ketones by using transition metal-mediated conditions.

摘要

相似文献

1
Synthesis of Trifluoromethylthiolated Alkenes and Ketones by Decarboxylative Functionalization of Cinnamic Acids.
Chem Asian J. 2016 Oct 20;11(20):2854-2858. doi: 10.1002/asia.201601098. Epub 2016 Sep 15.
2
Cu(II)-Mediated Decarboxylative Trifluoromethylthiolation of α,β-Unsaturated Carboxylic Acids.铜(II)介导的α,β-不饱和羧酸的脱羧三氟甲基硫代反应。
J Org Chem. 2018 Jan 5;83(1):499-504. doi: 10.1021/acs.joc.7b02232. Epub 2017 Dec 15.
3
Peroxide promoted tunable decarboxylative alkylation of cinnamic acids to form alkenes or ketones under metal-free conditions.过氧化物促进肉桂酸的可调谐脱羧烷基化反应,在无金属条件下生成烯烃或酮。
Chem Commun (Camb). 2015 May 1;51(35):7546-9. doi: 10.1039/c5cc01762a.
4
Decarboxylative functionalization of cinnamic acids.肉桂酸的脱羧官能化。
Org Biomol Chem. 2015 Aug 14;13(30):8094-115. doi: 10.1039/c5ob00727e.
5
Copper-Assisted Oxidative Trifluoromethylthiolation of 2,3-Allenoic Acids with AgSCF.铜促进的 2,3-烯丙基酸与 AgSCF 的三氟甲基硫代反应。
Org Lett. 2017 Sep 1;19(17):4624-4627. doi: 10.1021/acs.orglett.7b02249. Epub 2017 Aug 15.
6
Tandem trifluoromethylthiolation/aryl migration of aryl alkynoates to trifluoromethylthiolated alkenes.芳基炔酸酯的串联三氟甲硫基化/芳基迁移反应合成三氟甲硫基化烯烃
Chem Commun (Camb). 2017 Sep 12;53(73):10136-10139. doi: 10.1039/c7cc06232j.
7
Copper-mediated oxidative trifluoromethylthiolation of unactivated terminal alkenes.铜介导的未活化末端烯烃的氧化三氟甲硫基化反应。
Chem Commun (Camb). 2014 Nov 25;50(91):14157-60. doi: 10.1039/c4cc07062c.
8
Copper-Catalyzed, Stereoselective Bis-trifluoromethylthiolation of Propiolic Acid Derivatives with AgSCF.铜催化,AgSCF 促进丙炔酸衍生物的立体选择性双三氟甲基化反应。
Org Lett. 2017 Jun 16;19(12):3247-3250. doi: 10.1021/acs.orglett.7b01366. Epub 2017 Jun 2.
9
Silver-Mediated Oxidative Decarboxylative Trifluoromethylthiolation of Coumarin-3-carboxylic Acids.银介导的香豆素-3-羧酸的氧化脱羧三氟甲基化反应。
Org Lett. 2017 Feb 3;19(3):638-641. doi: 10.1021/acs.orglett.6b03806. Epub 2017 Jan 23.
10
A Direct Metal-Free Decarboxylative Sulfono Functionalization (DSF) of Cinnamic Acids to α,β-Unsaturated Phenyl Sulfones.肉桂酸向α,β-不饱和苯基砜的直接无金属脱羧磺酰基官能团化反应(DSF)
Org Lett. 2015 Jun 5;17(11):2656-9. doi: 10.1021/acs.orglett.5b01037. Epub 2015 May 8.

引用本文的文献

1
α-Selective -Carbotrifluoromethylthiolation of Alkynes.炔烃的α-选择性-三氟甲硫基化反应
Org Lett. 2025 Mar 14;27(10):2498-2503. doi: 10.1021/acs.orglett.5c00570. Epub 2025 Mar 3.
2
Cascade trifluoromethylthiolation and cyclization of -[(3-aryl)propioloyl]indoles.-[(3-芳基)丙炔酰基]吲哚的串联三氟甲硫基化和环化反应
Beilstein J Org Chem. 2020 Apr 8;16:657-662. doi: 10.3762/bjoc.16.62. eCollection 2020.