Li Huan, Liu Shuai, Huang Yangen, Xu Xiu-Hua, Qing Feng-Ling
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, 2999 North Renmin Lu, Shanghai 201620, China.
Chem Commun (Camb). 2017 Sep 12;53(73):10136-10139. doi: 10.1039/c7cc06232j.
A trifluoromethylthiolation initiated aryl migration of aryl alkynoates was disclosed. This protocol employs AgSCF as the SCF source and MeCN as both the solvent and the hydrogen source. This provides a new access to trifluoromethylthiolated alkenes from readily available substrates and reagents.
公开了一种由三氟甲硫基化引发的芳基炔酸酯的芳基迁移反应。该方法使用AgSCF作为三氟甲硫基源，乙腈既作为溶剂又作为氢源。这为从易得的底物和试剂制备三氟甲硫基化烯烃提供了一种新方法。
