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声化学理论。

Theory of Sonochemistry.

机构信息

School of Chemistry, University of Melbourne, Victoria, 3010, Australia.

出版信息

Top Curr Chem (Cham). 2016 Aug;374(4):56. doi: 10.1007/s41061-016-0054-y. Epub 2016 Aug 1.

Abstract

Sonochemistry refers to ultrasound-initiated chemical processes in liquids. The interaction between bubbles and sound energy in liquids results in acoustic cavitation. This review presents the fundamental aspects of acoustic cavitation and theoretical aspects behind sonochemistry such as dynamics of bubble oscillation, the rectified diffusion process that is responsible for the growth of cavitation bubbles, near adiabatic collapse of cavitation bubbles resulting in extreme reaction conditions and several chemical species generated within collapsing bubbles that are responsible for various redox reactions. Specifically, a detailed discussion on single bubble sonochemistry is provided.

摘要

声化学是指在液体中超声引发的化学过程。液体中气泡与声能的相互作用导致声空化。本综述介绍了声空化的基本方面和声化学的理论方面,如气泡振动的动力学、负责空化气泡生长的整流扩散过程、空化气泡的近绝热崩溃导致极端反应条件以及在崩溃气泡内产生的几种负责各种氧化还原反应的化学物质。具体来说,提供了关于单个气泡声化学的详细讨论。

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