McKetta Department of Chemical Engineering and Texas Materials Institute, Center for Energy and Environmental Resources, The University of Texas at Austin, 10100 Burnet Road, Building 133, Austin, TX, 78758, USA.
Joint Center for Artificial Photosynthesis, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, 30-210C, Berkeley, CA, 94702, USA.
Angew Chem Int Ed Engl. 2017 Apr 18;56(17):4662-4711. doi: 10.1002/anie.201601509. Epub 2017 Mar 22.
Polymeric membranes are an energy-efficient means of purifying water, but they suffer from fouling during filtration. Modification of the membrane surface is one route to mitigating membrane fouling, as it helps to maintain high levels of water productivity. Here, a series of common techniques for modification of the membrane surface are reviewed, including surface coating, grafting, and various treatment techniques such as chemical treatment, UV irradiation, and plasma treatment. Historical background on membrane development and surface modification is also provided. Finally, polydopamine, an emerging material that can be easily deposited onto a wide variety of substrates, is discussed within the context of membrane modification. A brief summary of the chemistry of polydopamine, particularly as it may pertain to membrane development, is also described.
聚合物膜是一种高效节能的水净化方法,但在过滤过程中会受到污染。通过对膜表面进行改性可以减轻膜污染,因为这有助于保持较高的产水率。本文综述了一系列常见的膜表面改性技术,包括表面涂层、接枝以及各种处理技术,如化学处理、紫外辐射和等离子体处理。本文还提供了膜开发和表面改性的历史背景。最后,本文还讨论了聚多巴胺作为一种新兴材料,它可以很容易地沉积在各种基质上,在膜改性方面的应用。本文还简要描述了聚多巴胺的化学性质,特别是其与膜开发的关系。