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VO-C-SnO混合纳米带作为锂离子电池的高性能阳极

VO-C-SnO Hybrid Nanobelts as High Performance Anodes for Lithium-ion Batteries.

作者信息

Zhang Linfei, Yang Mingyang, Zhang Shengliang, Wu Zefei, Amini Abbas, Zhang Yi, Wang Dongyong, Bao Shuhan, Lu Zhouguang, Wang Ning, Cheng Chun

机构信息

Department of Materials Science and Engineering and Shenzhen Key Laboratory of Nanoimprint Technology, South University of Science and Technology, Shenzhen 518055, China.

Single-Molecule Detection and Imaging Laboratory, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055, China.

出版信息

Sci Rep. 2016 Sep 28;6:33597. doi: 10.1038/srep33597.

Abstract

The superior performance of metal oxide nanocomposites has introduced them as excellent candidates for emerging energy sources, and attracted significant attention in recent years. The drawback of these materials is their inherent structural pulverization which adversely impacts their performance and makes the rational design of stable nanocomposites a great challenge. In this work, functional VO-C-SnO hybrid nanobelts (VCSNs) with a stable structure are introduced where the ultradispersed SnO nanocrystals are tightly linked with glucose on the VO surface. The nanostructured VO acts as a supporting matrix as well as an active electrode component. Compared with existing carbon-VO hybrid nanobelts, these hybrid nanobelts exhibit a much higher reversible capacity and architectural stability when used as anode materials for lithium-ion batteries. The superior cyclic performance of VCSNs can be attributed to the synergistic effects of SnO and VO. However, limited data are available for VO-based anodes in lithium-ion battery design.

摘要

金属氧化物纳米复合材料的卓越性能使其成为新兴能源的理想候选材料,并在近年来引起了广泛关注。这些材料的缺点是其固有的结构粉碎,这对其性能产生不利影响,并使得合理设计稳定的纳米复合材料成为一项巨大挑战。在这项工作中,引入了具有稳定结构的功能性VO-C-SnO混合纳米带(VCSNs),其中超分散的SnO纳米晶体与VO表面的葡萄糖紧密相连。纳米结构的VO既作为支撑基质,又作为活性电极组件。与现有的碳-VO混合纳米带相比,这些混合纳米带用作锂离子电池的负极材料时,表现出更高的可逆容量和结构稳定性。VCSNs优异的循环性能可归因于SnO和VO的协同效应。然而,在锂离子电池设计中,基于VO的负极材料的数据有限。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15bf/5039413/cf105450da1c/srep33597-f1.jpg

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