Cigada A, Rondelli G, Vicentini B, Giacomazzi M, Roos A
Dipartimento di Chimica Fisica Applicata, Politecnico di Milano, Italy.
J Biomed Mater Res. 1989 Sep;23(9):1087-95. doi: 10.1002/jbm.820230908.
The austenitic stainless steels used today for the manufacture of osteosynthesis devices are sensitive to crevice corrosion. In this study the corrosion properties of some duplex stainless steels were evaluated and compared to traditional austenitic stainless steels. According to our results the following ranking was established: 23Cr-4Ni less than AISI 316L less than ASTM F138 less than 22Cr-5Ni-3Mo less than 27Cr-31Ni-3.5Mo less than 25Cr-7Ni-4Mo-N. In particular the results showed that the high-performance 25Cr-7Ni-4Mo-N duplex stainless steel, with high molybdenum and nitrogen contents, can be considered not susceptible to crevice corrosion in the human body. The duplex stainless steels have also better mechanical properties at the same degree of cold working compared with austenitic stainless steels. Hence the 25Cr-7Ni-4Mo-N duplex stainless steel can be considered a convenient substitute of ASTM F138 for orthopedic and osteosynthesis devices.
如今用于制造骨固定器械的奥氏体不锈钢对缝隙腐蚀敏感。在本研究中,对一些双相不锈钢的腐蚀性能进行了评估,并与传统奥氏体不锈钢进行了比较。根据我们的结果,建立了以下排序:23Cr - 4Ni < AISI 316L < ASTM F138 < 22Cr - 5Ni - 3Mo < 27Cr - 31Ni - 3.5Mo < 25Cr - 7Ni - 4Mo - N。特别是结果表明,具有高钼和氮含量的高性能25Cr - 7Ni - 4Mo - N双相不锈钢在人体中可被认为不易发生缝隙腐蚀。与奥氏体不锈钢相比,双相不锈钢在相同冷加工程度下也具有更好的机械性能。因此,25Cr - 7Ni - 4Mo - N双相不锈钢可被认为是ASTM F138用于骨科和骨固定器械的便利替代品。