Platt J A, Guzman A, Zuccari A, Thornburg D W, Rhodes B F, Oshida Y, Moore B K
Department of Restorative Dentistry, Indiana University School of Dentistry, Indianapolis 46202-5186, USA.
Am J Orthod Dentofacial Orthop. 1997 Jul;112(1):69-79. doi: 10.1016/s0889-5406(97)70276-2.
The corrosion of 2205 duplex stainless steel was compared with that of AISI type 316L stainless steel. The 2205 stainless steel is a potential orthodontic bracket material with low nickel content (4 to 6 wt%), whereas the 316L stainless steel (nickel content: 10 to 14 wt%) is a currently used bracket material. Both stainless steels were subjected to electrochemical and immersion (crevice) corrosion tests in 37 degrees C, 0.9 wt% sodium chloride solution. Electrochemical testing indicates that 2205 has a longer passivation range than 316L. The corrosion rate of 2205 was 0.416 MPY (milli-inch per year), whereas 316L exhibited 0.647 MPY. When 2205 was coupled to 316L with equal surface area ratio, the corrosion rate of 2205 reduced to 0.260 MPY, indicating that 316L stainless steel behaved like a sacrificial anode. When 316L is coupled with NiTi, TMA, or stainless steel arch wire and was subjected to the immersion corrosion test, it was found that 316L suffered from crevice corrosion. On the other hand, 2205 stainless steel did not show any localized crevice corrosion, although the surface of 2205 was covered with corrosion products, formed when coupled to NiTi and stainless steel wires. This study indicates that considering corrosion resistance, 2205 duplex stainless steel is an improved alternative to 316L for orthodontic bracket fabrication when used in conjunction with titanium, its alloys, or stainless steel arch wires.
将2205双相不锈钢的腐蚀情况与AISI 316L型不锈钢进行了比较。2205不锈钢是一种潜在的正畸托槽材料,镍含量低(4至6 wt%),而316L不锈钢(镍含量:10至14 wt%)是目前使用的托槽材料。两种不锈钢都在37℃、0.9 wt%氯化钠溶液中进行了电化学和浸泡(缝隙)腐蚀试验。电化学测试表明,2205的钝化范围比316L长。2205的腐蚀速率为0.416 MPY(每年密耳英寸),而316L的腐蚀速率为0.647 MPY。当2205与316L以相等的表面积比耦合时,2205的腐蚀速率降至0.260 MPY,表明316L不锈钢表现得像牺牲阳极。当316L与镍钛合金、TMA或不锈钢弓丝耦合并进行浸泡腐蚀试验时,发现316L遭受缝隙腐蚀。另一方面,2205不锈钢没有出现任何局部缝隙腐蚀,尽管2205的表面覆盖有与镍钛合金和不锈钢丝耦合时形成的腐蚀产物。这项研究表明,考虑到耐腐蚀性,当与钛及其合金或不锈钢弓丝一起使用时,2205双相不锈钢是用于正畸托槽制造的比316L更好的替代品。