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有机阳离子对于卤铅钙钛矿中带边载流子的显著性质可能并非必需。

Organic Cations Might Not Be Essential to the Remarkable Properties of Band Edge Carriers in Lead Halide Perovskites.

机构信息

Department of Chemistry, Columbia University, New York, NY, 10027, USA.

Department of Chemistry, University of Wisconsin-Madison, Madison, WI, 53706, USA.

出版信息

Adv Mater. 2017 Jan;29(1). doi: 10.1002/adma.201603072. Epub 2016 Oct 28.

DOI:10.1002/adma.201603072
PMID:27792264
Abstract

A charge carrier in a lead halide perovskite lattice is protected as a large polaron responsible for the remarkable photophysical properties, irrespective of the cation type. All-inorganic-based APbX perovskites may mitigate the stability problem for their applications in solar cells and other optoelectronics.

摘要

在卤铅钙钛矿晶格中的电荷载流子被保护为大极化子，负责显著的光物理性质，而与阳离子类型无关。全无机基 APbX 钙钛矿可能缓解其在太阳能电池和其他光电子学中的应用的稳定性问题。

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