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有机共晶:分子协同创新的新策略。

Organic Cocrystals: New Strategy for Molecular Collaborative Innovation.

机构信息

Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University & Collaborative Innovation Center of Chemical Science and Engineering, Tianjin, 300072, People's Republic of China.

Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Zhongguancun, Beijing, 100190, People's Republic of China.

出版信息

Top Curr Chem (Cham). 2016 Dec;374(6):83. doi: 10.1007/s41061-016-0081-8. Epub 2016 Nov 24.

Abstract

Organic cocrystals that are composed of two or more components usually exhibit novel, unpredictable, and even unique properties rather than a simple combination of the properties of their components, such as white-light emission, ambipolar charge transport, nonlinear optics, and ferroelectricity. Since cocrystal engineering represents a novel strategy for synthesizing multifunctional materials, which opens the door for molecular collaborative innovation, it has aroused much attention in recent years. However, as it is also a relatively new research field, it is only in its early stages of development. In order to provide readers with an understanding of the future design of cocrystals for potential applications, a brief review of organic cocrystals is presented here, including an introduction to organic cocrystals as well as discussions of cocrystal preparation, methods and techniques of characterization, and multifunctional applications of cocrystals. Moreover, the outlook for further studies and applications of cocrystal engineering is considered.

摘要

有机共晶由两个或多个组分组成,通常表现出新颖、不可预测甚至独特的性质,而不是其组分性质的简单组合,例如白光发射、双极性电荷输运、非线性光学和铁电性。由于共晶工程代表了一种合成多功能材料的新策略,为分子协同创新开辟了道路,近年来引起了广泛关注。然而,由于它也是一个相对较新的研究领域,目前仍处于发展的早期阶段。为了使读者了解未来潜在应用的共晶设计,本文简要综述了有机共晶,包括有机共晶的介绍以及对共晶制备、性质表征方法和技术以及共晶多功能应用的讨论。此外,还考虑了共晶工程进一步研究和应用的前景。

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